A mixture of CO2 and Kr weighs 35.0 g and exerts a

Chapter 6, Problem 95P

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QUESTION: Problem 95P

A mixture of CO2 and Kr weighs 35.0 g and exerts a pressure of 0.708 atm in its container. Since Kr is expensive, you wish to recover it from the mixture. After the CO2 is completely removed by absorption with NaOH(s), the pressure in the container is 0.250 atm. How many grams of CO2 were originally present? How many grams of Kr can you recover?

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QUESTION: Problem 95P

A mixture of CO2 and Kr weighs 35.0 g and exerts a pressure of 0.708 atm in its container. Since Kr is expensive, you wish to recover it from the mixture. After the CO2 is completely removed by absorption with NaOH(s), the pressure in the container is 0.250 atm. How many grams of CO2 were originally present? How many grams of Kr can you recover?

ANSWER:

Solution 95P:

Step 1:

Here, we are going to calculate the mass of CO2(g) originally present in the mixture.

Given that

Total mass of the mixture =35.0 g

Let us consider, the mass of CO2(g) and Kr are x and y respectively

Thus,

Total pressure =0.708 atm

Let us consider P1 and P2 are the partial pressures of Kr and CO2 respectively.

Since,

From the ideal gas equation

For Kr gas,

----(3)

For CO2 (g)

----(4)

Therefore, putting the values of (3) and (4) in (2) we get

(----(5)

Now, we know that

Moles of gas =

Thus (5) implies

(

) =0.708 ---(6)

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