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A mixture of CO2 and Kr weighs 35.0 g and exerts a
Chapter 6, Problem 95P(choose chapter or problem)
A mixture of CO2 and Kr weighs 35.0 g and exerts a pressure of 0.708 atm in its container. Since Kr is expensive, you wish to recover it from the mixture. After the CO2 is completely removed by absorption with NaOH(s), the pressure in the container is 0.250 atm. How many grams of CO2 were originally present? How many grams of Kr can you recover?
Questions & Answers
QUESTION: Problem 95P
A mixture of CO2 and Kr weighs 35.0 g and exerts a pressure of 0.708 atm in its container. Since Kr is expensive, you wish to recover it from the mixture. After the CO2 is completely removed by absorption with NaOH(s), the pressure in the container is 0.250 atm. How many grams of CO2 were originally present? How many grams of Kr can you recover?
ANSWER:
Solution 95P:
Step 1:
Here, we are going to calculate the mass of CO2(g) originally present in the mixture.
Given that
Total mass of the mixture =35.0 g
Let us consider, the mass of CO2(g) and Kr are x and y respectively
Thus,
Total pressure =0.708 atm
Let us consider P1 and P2 are the partial pressures of Kr and CO2 respectively.
Since,
From the ideal gas equation
For Kr gas,
----(3)
For CO2 (g)
----(4)
Therefore, putting the values of (3) and (4) in (2) we get
(----(5)
Now, we know that
Moles of gas =
Thus (5) implies
(
) =0.708 ---(6)