(a) If Kw = 1.139×10-15at 0°C and 5.474X 10-14 at 50°C,

Chapter 18, Problem 111P

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Problem 111P

(a) If Kw = 1.139×10-15at 0°C and 5.474X 10-14 at 50°C, find [H3O+] and pH of water at 0°C and 50°C.

(b)The autoionization constant for heavy water (deuterium oxide, D2O) is 3.64×10-2 at 0°C and 7.89×10-15 at 50°C. Find [D3O+] and pD of heavy water at 0°C and 50°C.

(c)Suggest a reason for these differences.

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