Consider the following values for enthalpy of vaporization (kJ/mol) of several organic

Chapter 13, Problem 13.106

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Consider the following values for enthalpy of vaporization (kJ/mol) of several organic substances: 0 II H2C..--O...._ CH3C-H 30.4 CH2 28.5 Acetaldehyde Ethylene oxide 0 II CH CH3CCH3 32.0 H2C..-- 2... ._CH2 24.7 Acetone Cyclopropane (a) Use variations in the intermolecular forces operating in these organic liquids to account for their variations in heats of vaporization. (b) How would you expect the solubilities of these substances to vary in hexane as solvent? 1n ethanol? Use intermolecular forces, including hydrogen-bonding interactions where applicable, to explain your responses.

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