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Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward
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The reaction was studied with the following results:ClO 2 -(aq) + H2O(l) +(a) Determine

Chapter 20, Problem 14.34

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QUESTION:

The reaction was studied with the following results:

               

(a) Determine the rate law for the reaction.

(b) Calculate the rate constant with proper units.

(c) Calculate the rate when  and .

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QUESTION:

The reaction was studied with the following results:

               

(a) Determine the rate law for the reaction.

(b) Calculate the rate constant with proper units.

(c) Calculate the rate when  and .

ANSWER:

Step 1 of 4

Determine the order of reaction concerning the reactants.

Calculating the order of the reaction with respect to .

                                             

Here, n represents the order of the reaction with respect to .

Substitute the concentration of   at which the remains constant and initial rates corresponding to them in equation (I).

                                               

To simplify the calculations, 8.98 can be approximated as 9.

Therefore,

                                                                           

The order of the reaction with respect to  is 2.

 

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