(a) Chlorocyclohexane contains 2.07 times more of the equatorial form than the axial

Chapter 7, Problem 7.39

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(a) Chlorocyclohexane contains 2.07 times more of the equatorial form than the axial form at equilibrium at 25 C. What is the standard free-energy difference between the two forms? Which is more stable? (b) The standard free-energy difference between the two chair conformations of isopropylcyclohexane is 9.2 kJ mol1 (2.2 kcal mol1 ). What is the ratio of concentrations of the two conformations at 25 C?

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