(a) What is the ratio of rate constants kAykB at 25 C for two reactions A and B if the

Chapter 9, Problem 9.7

(choose chapter or problem)

(a) What is the ratio of rate constants kAykB at 25 C for two reactions A and B if the standard free energy of activation of reaction A is 14 kJ mol1 (3.4 kcal mol1 ) less than that of reaction B? (b) What is the difference in the standard free energies of activation at 25 C of two reactions A and B if reaction B is 450 times faster than reaction A? Which reaction has the greater DG?

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