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Solutions for Chapter 14: Ethers and Epoxides; Thiols and Sulfides

Organic Chemistry,  - Standalone Book | 2nd Edition | ISBN: 9781118452288 | Authors: David R. Klein

Full solutions for Organic Chemistry, - Standalone Book | 2nd Edition

ISBN: 9781118452288

Organic Chemistry,  - Standalone Book | 2nd Edition | ISBN: 9781118452288 | Authors: David R. Klein

Solutions for Chapter 14: Ethers and Epoxides; Thiols and Sulfides

Solutions for Chapter 14
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Textbook: Organic Chemistry, - Standalone Book
Edition: 2
Author: David R. Klein
ISBN: 9781118452288

This expansive textbook survival guide covers the following chapters and their solutions. Organic Chemistry, - Standalone Book was written by Patricia and is associated to the ISBN: 9781118452288. Chapter 14: Ethers and Epoxides; Thiols and Sulfides includes 72 full step-by-step solutions. This textbook survival guide was created for the textbook: Organic Chemistry, - Standalone Book, edition: 2. Since 72 problems in chapter 14: Ethers and Epoxides; Thiols and Sulfides have been answered, more than 15171 students have viewed full step-by-step solutions from this chapter.

Key Chemistry Terms and definitions covered in this textbook
  • alternating copolymers

    A copolymer that contains an alternating distribution of repeating units.

  • bar

    A unit of pressure equal to 105 Pa. (Section 10.2)

  • Beer’s law

    The light absorbed by a substance (A) equals the product of its extinction coefficient 1e2, the path length through which the light passes (b), and the molar concentration of the substance (c): A = ebc. (Section 14.2)

  • bonding pair

    In a Lewis structure a pair of electrons that is shared by two atoms. (Section 9.2)

  • Dalton’s law of partial pressures.

    The total pressure of a mixture of gases is just the sum of the pressures that each gas would exert if it were present alone. (5.6)

  • dextrorotatory, or merely dextro or d

    A term used to label a chiral molecule that rotates the plane of polarization of plane-polarized light to the right (clockwise). (Section 23.4)

  • diagonal relationship.

    Similarities between pairs of elements in different groups and periods of the periodic table. (8.6)

  • ester

    An organic compound that has an OR group attached to a carbonyl; it is the product of a reaction between a carboxylic acid and an alcohol. (Section 24.4)

  • fission

    The splitting of a large nucleus into two smaller ones. (Section 21.6)

  • Gibbs free energy change (DG°)

    The energy that dictates the position of chemical equilibria and rates of chemical reactions. A thermodynamic function of enthalpy, entropy, and temperature, given by the equation DG° 5 DH° 2 TDS°. If DG° , 0, the position of equilibria for the reaction favors products. If DG° . 0, the position of equilibria favors reactants.

  • Homotopic groups

    Atoms or groups on an atom that give an achiral molecule when one of the groups is replaced by another group. The hydrogens of the CH2 group of propane, for example, are homotopic. Replacing either one of them with deuterium gives 2-deuteropropane, which is achiral. Homotopic groups have identical chemical shifts under all conditions

  • ionic hydrides

    Compounds formed when hydrogen reacts with alkali metals and also the heavier alkaline earths (Ca, Sr, and Ba); these compounds contain the hydride ion, H-. (Section 22.2)

  • migratory aptitude

    In a BaeyerVilliger oxidation, the migration rates of different groups, which determine the regiochemical outcome of the reaction.

  • nematic liquid crystalline phase

    A liquid crystal in which the molecules are aligned in the same general direction, along their long axes, but in which the ends of the molecules are not aligned. (Section 11.7)

  • norbornane

    The common name for bicyclo[2.2.1]heptane.

  • nucleon

    A particle found in the nucleus of an atom. (Section 21.1)

  • phosphoglycerides

    Compounds that are very similar in structure to triglycerides, with the main difference being that one of the three fatty acid residues is replaced by a phosphoester group.

  • Polyamide

    A polymer in which each monomer unit is joined to the next by an amide bond, as, for example, nylon 66.

  • simple lipid

    A lipid that does not undergo hydrolysis in aqueous acid or base to produce smaller fragments.

  • Watson-Crick model

    A double-helix model for the secondary structure of a DNA molecule

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