Solutions for Chapter 13: Organic Chemistry 6th Edition

Organic Chemistry | 6th Edition | ISBN: 9780840054982 | Authors: William H. Brown and Lawrence S. Brown

Full solutions for Organic Chemistry | 6th Edition

ISBN: 9780840054982

Organic Chemistry | 6th Edition | ISBN: 9780840054982 | Authors: William H. Brown and Lawrence S. Brown

Solutions for Chapter 13

Solutions for Chapter 13
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Textbook: Organic Chemistry
Edition: 6
Author: William H. Brown and Lawrence S. Brown
ISBN: 9780840054982

Since 26 problems in chapter 13 have been answered, more than 17531 students have viewed full step-by-step solutions from this chapter. Organic Chemistry was written by Sieva Kozinsky and is associated to the ISBN: 9780840054982. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 6. This expansive textbook survival guide covers the following chapters and their solutions. Chapter 13 includes 26 full step-by-step solutions.

Key Chemistry Terms and definitions covered in this textbook
  • aliphatic hydrocarbons.

    Hydrocarbons that do not contain the benzene group or the benzene ring. (24.1)

  • chain branching

    During polymerization, the growth of a branch connected to the main chain.

  • covalent compounds.

    Compounds containing only covalent bonds. (9.4)

  • Curved arrow

    A symbol used to show the redistribution of valence electrons in resonance contributing structures or reactions, symbolizing movement of two electrons

  • d-Monosaccharide

    A monosaccharide that, when written as a Fischer projection, has the !OH on its penultimate carbon to the right.

  • electrolyte

    A solute that produces ions in solution; an electrolytic solution conducts an electric current. (Section 4.1)

  • galvanic cell

    See voltaic cell. (Section 20.3)

  • Hammond postulate

    In an exothermic process the transition state is closer in energy to the reactants than to the products, and therefore the structure of the transition state more closely resembles the reactants. In contrast, the transition state in an endothermic process is closer in energy to the products, and therefore the transition state more closely resembles the products.

  • heterolytic bond cleavage

    Bond breaking that results in the formation of ions.

  • inversion of configuration

    During a reaction, when the configuration of a chirality center is changed.

  • ketone

    A compound in which the carbonyl group 1C “O2 occurs at the interior of a carbon chain and is therefore flanked by carbon atoms. (Section 24.4)

  • Lindlar catalyst

    Finely powdered palladium metal deposited on solid calcium carbonate that has been specially modifi ed with lead salts. Its particular use is as a catalyst for the reduction of an alkyne to a cis alkene

  • N terminus

    For a peptide chain,the end that contains the amino group.

  • potential energy

    The energy that an object possesses as a result of its composition or its position with respect to another object. (Section 5.1)

  • progestins

    Female sex hormones.

  • Protecting group

    Reversibly creating an unreactive group for the purpose of preventing a functional group from potentially reacting to give an unwanted product or products

  • redox (oxidation–reduction) reaction

    A reaction in which certain atoms undergo changes in oxidation states. The substance increasing in oxidation state is oxidized; the substance decreasing in oxidation state is reduced. (Section 4.4; Chapter 20: Introduction)

  • staggered conformation

    A conformation in which nearby groups in a Newman projection have a dihedral angle of 60°.

  • sulfonate ions

    Common leaving groups. Examples include tosylate, mesylate, and triflate ions.

  • vicinal

    A term used to describe two identical groups attached to adjacent carbon atoms.

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