- 13.13.3: Each compound gives only one signal in its 1 H-NMR spectrum. Propos...
- 13.13.4: The line of integration of the two signals in the 1 H-NMR spectrum ...
- 13.13.5: Following are two constitutional isomers with the molecular formula...
- 13.13.6: Following are pairs of constitutional isomers. Predict the number o...
- 13.13.7: Following is a 1 H-NMR spectrum of 2-butanol. Explain why the CH2 p...
- 13.13.8: Explain how to distinguish between the members of each pair of cons...
- 13.13.9: Calculate the index of hydrogen defi ciency of these compounds. (a)...
- 13.13.1: Complete the following table. Which nucleus requires the least ener...
- 13.13.11: The natural abundance of 13C is only 1.1%. Furthermore, its sensiti...
- 13.13.12: Following are structural formulas for three constitutional isomers ...
- 13.13.13: Following are structural formulas for the cis isomers of 1,2-, 1,3-...
- 13.13.14: Following are structural formulas, dipole moments, and 1 H-NMR chem...
- 13.13.15: Following are three compounds with the molecular formula C4H8O2, an...
- 13.13.16: Following are 1 H-NMR spectra for compounds D, E, and F, each with ...
- 13.13.17: Following are 1 H-NMR spectra for compounds G, H, and I, each with ...
- 13.13.18: Propose a structural formula for compound J, molecular formula C3H6...
- 13.13.19: Compound K, molecular formula C6H14O, readily undergoes acid-cataly...
- 13.13.2: Compound M, molecular formula C5H10O, readily decolorizes Br2 in CC...
- 13.13.21: Following is the 1 H-NMR spectrum of compound O, molecular formula ...
- 13.13.22: Treatment of compound P with BH3 followed by H2O2/NaOH gives compou...
- 13.13.23: The 1 H-NMR of compound R, C6H14O, consists of two signals: d 1.1 (...
- 13.13.24: Write structural formulas for the following compounds. (a) C2H4Br2:...
- 13.13.25: The percent s-character of carbon participating in a C!H bond can b...
- 13.12.26: Ascaridole is a natural product that has been used to treat intesti...
- 13.13.27: The 13C-NMR spectrum of 3-methyl-2-butanol shows signals at d 17.88...
- 13.13.28: Sketch the NMR spectrum you would expect from a partial molecule wi...
Solutions for Chapter 13: Organic Chemistry 6th Edition
Full solutions for Organic Chemistry | 6th Edition
Steric interactions that occur between axial substituents in a chair conformation.
Hydrocarbons containing one or more carbon–carbon double bonds. (Section 24.2)
A compound that contains both an amino group and a carboxyl group
When applying Woodward-Fieser rules, the groups attached to the chromophore.
A bond in which two electrons are shared by two atoms. (9.4)
Solids in which the units that make up the three-dimensional network are joined by covalent bonds. (Section 12.1)
In bond-line structures, agroup going behind the page.
Female sex hormones.
A hydrogen atom with two electrons in its valence shell; H:!
hydrogen deficiency index (HDI)
A measure of the number of degrees of unsaturation in a compound.
inversion of configuration
During a reaction, when the configuration of a chirality center is changed.
Atoms of the same element containing different numbers of neutrons and therefore having different masses. (Section 2.3)
The electrophile in a Michael reaction.
A reaction that is performed with photochemical excitation (usually UV light).
pi 1P2 bond
A covalent bond in which electron density is concentrated above and below the internuclear axis. (Section 9.6)
A device that measures the rotation of plane-polarized light caused by optically active compounds.
The ability of an atom or molecule to distribute its electron density unevenly in response to external influences.
A reaction in which an atom or group of atoms in a compound is replaced by another atom or group of atoms.
Tertiary (3°) amine
An amine in which nitrogen is bonded to three carbons
A signal of an NMR spectrum that is shifted toward the right (smaller chemical shift) on the chart paper.