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Solutions for Chapter 28: Organic Chemistry 6th Edition

Organic Chemistry | 6th Edition | ISBN: 9780840054982 | Authors: William H. Brown, Christopher S. Foote , Brent L. Iverson, Eric Anslyn

Full solutions for Organic Chemistry | 6th Edition

ISBN: 9780840054982

Organic Chemistry | 6th Edition | ISBN: 9780840054982 | Authors: William H. Brown, Christopher S. Foote , Brent L. Iverson, Eric Anslyn

Solutions for Chapter 28

Solutions for Chapter 28
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Textbook: Organic Chemistry
Edition: 6
Author: William H. Brown, Christopher S. Foote , Brent L. Iverson, Eric Anslyn
ISBN: 9780840054982

This textbook survival guide was created for the textbook: Organic Chemistry, edition: 6. Since 38 problems in chapter 28 have been answered, more than 80502 students have viewed full step-by-step solutions from this chapter. Chapter 28 includes 38 full step-by-step solutions. This expansive textbook survival guide covers the following chapters and their solutions. Organic Chemistry was written by and is associated to the ISBN: 9780840054982.

Key Chemistry Terms and definitions covered in this textbook
  • absorbance

    In UV-Vis spectroscopy, the value log (I0/I) where I0 is the intensity of the reference beam and I is the intensity of the sample beam.

  • adhesion.

    Attraction between unlike molecules. (11.3)

  • alloy

    A substance that has the characteristic properties of a metal and contains more than one element. Often there is one principal metallic component, with other elements present in smaller amounts. Alloys may be homogeneous or heterogeneous. (Section 12.3)

  • Chemical shift (d)

    The shift in parts per million of an NMR signal relative to the signal of TMS

  • compound.

    A substance composed of atoms of two or more elements chemically united in fixed proportions. (1.4)

  • Dalton’s law of partial pressures.

    The total pressure of a mixture of gases is just the sum of the pressures that each gas would exert if it were present alone. (5.6)

  • dextrorotatory

    A compound that rotates plane-polarized light in a clockwise direction (+).

  • disrotatory

    In electrocyclicreactions, a type of rotation in which the orbitalsbeing used to form the new s bond must rotate in opposite directions (one rotates clockwise while the other rotates counterclockwise).

  • Endothermic reaction

    A reaction in which the enthalpy of the products is higher than the enthalpy of the reactants; a reaction in which heat is absorbed

  • Functional group

    An atom or group of atoms within a molecule that shows a characteristic set of physical and chemical properties

  • Gauche conformation

    A conformation about a single bond of an alkane in which two groups on adjacent carbons lie at a dihedral angle of 60°

  • hyperconjugation

    An effect that explains why alkyl groups stabilize a carbocation.

  • keto-enol tautomerization

    The equilibrium that is established between an enol and a ketone in either acid-catalyzed or basecatalyzed conditions.

  • Melt transition (Tm)

    The temperature at which crystalline regions of a polymer melt.

  • Pericyclic reaction

    A reaction that takes place in a single step, without intermediates, and involves a cyclic redistribution of bonding electrons

  • Restriction endonuclease

    An enzyme that catalyzes the hydrolysis of a particular phosphodiester bond within a DNA strand.

  • reversible process

    A process that can go back and forth between states along exactly the same path; a system at equilibrium is reversible if equilibrium can be shifted by an infinitesimal modification of a variable such as temperature. (Section 19.1)

  • spontaneous

    A reaction with a negative DG, which means that products are favored at equilibrium.

  • Watson-Crick model

    A double-helix model for the secondary structure of a DNA molecule

  • Zwitterion

    An internal salt of an amino acid; the carboxylate is negatively charged, and the ammonium group is positively charged