Following is the mass spectrum of 1-bromobutane. (a)

Chapter 14, Problem 14.25

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Following is the mass spectrum of 1-bromobutane. (a) Account for the appearance of the M 1 2 peak of approximately 95% of the intensity of the molecular ion peak. (b) Propose structural formulas for the cations of m/z 57, 41, and 29. 558 Chapter 14 Mass Spectrometry 0 20 40 60 80 100 Relative Abundance m/z 160150140130120110100908070605040302010 MW = 136 H2CCH2CH2CH3 Br M (136) 29 41 57 138

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