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?The vapor pressure of ethanol \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\) and
Chapter 12, Problem 52P(choose chapter or problem)
The vapor pressure of ethanol \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\) and l-propanol \(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) at 35°C are 100 mmHg and 37.6 mmHg, respectively. Assume ideal behavior and calculate the partial pressures of ethanol and l-propanol at 35°C over a solution of ethanol in l-propanol, in which the mole fraction of ethanol is 0.300.
Questions & Answers
QUESTION:
The vapor pressure of ethanol \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}\) and l-propanol \(\mathrm{C}_{3} \mathrm{H}_{7} \mathrm{OH}\) at 35°C are 100 mmHg and 37.6 mmHg, respectively. Assume ideal behavior and calculate the partial pressures of ethanol and l-propanol at 35°C over a solution of ethanol in l-propanol, in which the mole fraction of ethanol is 0.300.
ANSWER:Step 1 of 2
The vapor pressure of the solvent over a solution is given by the product of the vapor pressure of the pure solvent and the mole fraction of the solvent in the solution is stated by Raoult's law.
where and are the partial pressures over the solution for components A and and are the vapor pressures of the pure substances; and and are their mole fractions.