The BOC-protecting group may be added by treatment of an
Chapter 27, Problem 27.52(choose chapter or problem)
The BOC-protecting group may be added by treatment of an amino acid with di-tert -butyl dicarbonate as shown in the following reaction sequence. Propose a mechanism to account for formation of these products. O O Di-tert-butyl dicarbonate BOC-amino acid (CH3)3COCOCOC(CH3)3 1 H2NCHCOO2 O (CH3)3COCNHCHCOO 1 (CH3)3COH 1 CO2 R R
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