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The phosphorus trihalides (PX3) show the following

Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward ISBN: 9780321696724 27

Solution for problem 111IE Chapter 9

Chemistry: The Central Science | 12th Edition

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Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward

Chemistry: The Central Science | 12th Edition

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Problem 111IE

The phosphorus trihalides (PX3) show the following variation in the bond angle X—P—X: PF3, 96.3°; PCl3, 100.3°; PBr3, 101.0°; PI3, 102.0°. The trend is generally attributed to the change in the electronegativity of the halogen. (a) Assuming that all electron domains are the same size, what value of the X—P—X angle is predicted by the VSEPR model? (b) What is the general trend in the X—P—X angle as the halide electronegativity increases? (c) Using the VSEPR model, explain the observed trend in X—P—X angle as the electronegativity of X changes., (d) Based on your answer to part (c), predict the structure of PBrCl4.

Step-by-Step Solution:
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Chapter 9, Problem 111IE is Solved
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Textbook: Chemistry: The Central Science
Edition: 12
Author: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward
ISBN: 9780321696724

Since the solution to 111IE from 9 chapter was answered, more than 397 students have viewed the full step-by-step answer. The full step-by-step solution to problem: 111IE from chapter: 9 was answered by , our top Chemistry solution expert on 04/03/17, 07:58AM. This textbook survival guide was created for the textbook: Chemistry: The Central Science, edition: 12. This full solution covers the following key subjects: electronegativity, angle, Trend, model, VSEPR. This expansive textbook survival guide covers 49 chapters, and 5471 solutions. The answer to “The phosphorus trihalides (PX3) show the following variation in the bond angle X—P—X: PF3, 96.3°; PCl3, 100.3°; PBr3, 101.0°; PI3, 102.0°. The trend is generally attributed to the change in the electronegativity of the halogen. (a) Assuming that all electron domains are the same size, what value of the X—P—X angle is predicted by the VSEPR model? (b) What is the general trend in the X—P—X angle as the halide electronegativity increases? (c) Using the VSEPR model, explain the observed trend in X—P—X angle as the electronegativity of X changes., (d) Based on your answer to part (c), predict the structure of PBrCl4.” is broken down into a number of easy to follow steps, and 103 words. Chemistry: The Central Science was written by and is associated to the ISBN: 9780321696724.

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