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(a) Compare the bond enthalpies (Table) of the carbon–

Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward ISBN: 9780321696724 27

Solution for problem 113IE Chapter 9

Chemistry: The Central Science | 12th Edition

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Chemistry: The Central Science | 12th Edition | ISBN: 9780321696724 | Authors: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward

Chemistry: The Central Science | 12th Edition

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Problem 113IE

(a) Compare the bond enthalpies (Table) of the carbon– carbon single, double, and triple bonds to deduce an average π-bond contribution to the enthalpy. What fraction of a single bond does this quantity represent?

Table Average Bond Enthalpies(kJ/mol)

Single Bonds

C—H

413

N—H

391

463

O—H

F—F

155

C—C

348

N—N

163

O—O

146

 

 

C—N

293

N—O

201

O—F

190

Cl—F

253

C—O

358

N—F

272

O—Cl

203

Cl—Cl

242

C—F

485

N—Cl

200

O—l

234

 

 

C—Cl

328

N—Br

243

 

 

Br—F

237

C—Br

276

 

 

S—H

339

Br—Cl

218

C—l

240

H—H

436

S—F

327

Br—Br

193

C—S

259

H—F

567

S—Cl

253

 

 

 

 

H—Cl

431

S—Br

218

I—Cl

208

Si—H

323

H—Br

366

S—S

266

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Chapter 9, Problem 113IE is Solved
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Textbook: Chemistry: The Central Science
Edition: 12
Author: Theodore E. Brown; H. Eugene LeMay; Bruce E. Bursten; Catherine Murphy; Patrick Woodward
ISBN: 9780321696724

This full solution covers the following key subjects: Bond, bonds, nitrogen, Single, carbon. This expansive textbook survival guide covers 49 chapters, and 5471 solutions. The answer to “(a) Compare the bond enthalpies (Table) of the carbon– carbon single, double, and triple bonds to deduce an average ?-bond contribution to the enthalpy. What fraction of a single bond does this quantity represent?Table Average Bond Enthalpies(kJ/mol)Single BondsC—H413N—H391463O—HF—F155C—C348N—N163O—O146 C—N293N—O201O—F190Cl—F253C—O358N—F272O—Cl203Cl—Cl242C—F485N—Cl200O—l234 C—Cl328N—Br243 Br—F237C—Br276 S—H339Br—Cl218C—l240H—H436S—F327Br—Br193C—S259H—F567S—Cl253 H—Cl431S—Br218I—Cl208Si—H323H—Br366S—S266I—Br175Si—Si226H—l299 I—l151Si—C301 Si—O368 Si—Cl464 Multiple BondsC?C614N?N418O?O495 C?C839N?N941 C?N615N?O607S?O523 C?N891 S?S418 C?O799 C?O1072 , (b) Make a similar comparison of nitrogen–nitrogen bonds. What do you observe? (c) Write Lewis structures of N2H4, N2H2, and N2, and determine the hybridization around nitrogen in each case., (d) Propose a reason for the large difference in your observations of parts (a) and (b).” is broken down into a number of easy to follow steps, and 101 words. The full step-by-step solution to problem: 113IE from chapter: 9 was answered by , our top Chemistry solution expert on 04/03/17, 07:58AM. Chemistry: The Central Science was written by and is associated to the ISBN: 9780321696724. This textbook survival guide was created for the textbook: Chemistry: The Central Science, edition: 12. Since the solution to 113IE from 9 chapter was answered, more than 318 students have viewed the full step-by-step answer.

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(a) Compare the bond enthalpies (Table) of the carbon–

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