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Answer: Determine the electron and molecular geometries of each molecule. For molecules
Chapter 10, Problem 73P(choose chapter or problem)
Determine the electron and molecular geometries of each molecule. For molecules with two central atoms, indicate the geometry about each central atom.
(a) \(N_2\)
(b) \(N_2H_2\) (skeletal structure HNNH)
(c) \(N_2H_4\) (skeletal structure \(H_2NNH_2\))
Questions & Answers
(1 Reviews)
QUESTION:
Determine the electron and molecular geometries of each molecule. For molecules with two central atoms, indicate the geometry about each central atom.
(a) \(N_2\)
(b) \(N_2H_2\) (skeletal structure HNNH)
(c) \(N_2H_4\) (skeletal structure \(H_2NNH_2\))
ANSWER:
Step 1 of 3
(a) The following table is used to identify the electron and molecular geometry of the molecule.
\(\begin{array}{|c|c|c|c|c|c|c|} \hline \begin{array}{l} \text { Electron } \\ \text { groups } \end{array} & \begin{array}{l} \text { Bonding } \\ \text { groups } \end{array} & \begin{array}{l} \text { Lone } \\ \text { pair } \end{array} & \begin{array}{l} \text { Electron } \\ \text { geometry } \end{array} & \begin{array}{l} \text { Angle } \\ \text { between } \\ \text { electron } \\ \text { groups } \end{array} & \begin{array}{l} \text { Molecular } \\ \text { geometry } \end{array} & \text { Example } \\ \hline 2 & 2 & 0 & \text { Linear } & 180^{\circ} & \text { Linear } & \mathrm{CO}_{2} \\ \hline 3 & 3 & 0 & \text { Trigonal planar } & 120^{\circ} & \text { Trigonal planar } & \mathrm{COH}_{2} \\ \hline 3 & 2 & 1 & \text { Trigonal planar } & 109.5^{\circ} & \text { Bent } & \mathrm{SO}_{3} \\ \hline 4 & 4 & 0 & \text { Tetrahedral } & 109.5^{\circ} & \text { Tetrahedral } & \mathrm{CH}_{4} \\ \hline 4 & 3 & 1 & \text { Tetrahedral } & 109.5^{\circ} & \text { Trigonal planar } & \mathrm{NH}_{3} \\ \hline 4 & 2 & 2 & \text { Tetrahedral } & 109.5^{\circ} & \text { Bent } & \mathrm{H}_{2} \mathrm{O} \\ \hline\end{array}\)
The Lewis structure of \(N_2\) is as follows.
It is a diatomic molecule. Each nitrogen atom has one electron pair and one lone pair. But it is a homogeneous diatomic molecule.
Hence, the electron and molecular geometry of the molecule are linear.
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