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Predict the approximate bond angles fora. the C-N-C bond

Chapter 1, Problem 42P

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QUESTION:

Predict the approximate bond angles for

a.  the \(\mathrm{C}-\mathrm{N}-\mathrm{C}\) bond angle in \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}_{2}\).

b.  the \(\mathrm{C}-\mathrm{N}-\mathrm{H}\) bond angle in \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{NH}_{2}\).

c.  the \(\mathrm{H}-\mathrm{C}-\mathrm{N}\) bond angle in \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}\).

d.  the \(\mathrm{H}-\mathrm{C}-\mathrm{O}\) bond angle in \(\mathrm{CH}_{3} \mathrm{OCH}_{3}\).

Questions & Answers

QUESTION:

Predict the approximate bond angles for

a.  the \(\mathrm{C}-\mathrm{N}-\mathrm{C}\) bond angle in \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}_{2}\).

b.  the \(\mathrm{C}-\mathrm{N}-\mathrm{H}\) bond angle in \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{NH}_{2}\).

c.  the \(\mathrm{H}-\mathrm{C}-\mathrm{N}\) bond angle in \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NH}\).

d.  the \(\mathrm{H}-\mathrm{C}-\mathrm{O}\) bond angle in \(\mathrm{CH}_{3} \mathrm{OCH}_{3}\).

ANSWER:

Step 1 of 4

Here we have to calculate the bond angle of the given molecule:-

(a)  C-N-C bond angle in

Here we have to calculate the C-N-C bond angle, the central atom N  hybridized with no lone pair , thus the bond angle is 109.5°.

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