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a. Explain why the reaction of an alkyl halide with

Chapter 9, Problem 16P

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QUESTION:

a. Explain why the reaction of an alkyl halide with ammonia gives a low yield of primary amine.

b. Explain why a much better yield of primary amine is obtained from the reaction of analkylhalide with azide ion (\(^-\text{N}_3\)), followed by catalytic hydrogenation. (Hint: An alkyl azide is not nucleophilic.)

Equation Transcription:

-N3

Text Transcription:

-N3

Questions & Answers

QUESTION:

a. Explain why the reaction of an alkyl halide with ammonia gives a low yield of primary amine.

b. Explain why a much better yield of primary amine is obtained from the reaction of analkylhalide with azide ion (\(^-\text{N}_3\)), followed by catalytic hydrogenation. (Hint: An alkyl azide is not nucleophilic.)

Equation Transcription:

-N3

Text Transcription:

-N3

ANSWER:

Solution 16P

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