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Answer: Acetylene (C2H2) and benzene (C6H6) have the same

Chapter 6, Problem 125P

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QUESTION:

Acetylene \(\left(\mathrm{C}_{2} \mathrm{H}_{2}\right)\) and benzene \(\left(C_{6} H_{6}\right)\) have the same empirical formula. In fact, benzene can be made from acetylene as follows:

\(3 \mathrm{C}_{2} \mathrm{H}_{2}(g) \rightarrow \mathrm{C}_{6} \mathrm{H}_{6}(l)\)

The enthalpies of combustion for \(\mathrm{C}_{2} \mathrm{H}_{2}\) and \(C_{6} H_{6}\) are - 1299.4 kJ/mol and -3267.4 kJ/mol, respectively. Calculate the standard enthalpies of formation of \(\mathrm{C}_{2} \mathrm{H}_{2}\) and \(C_{6} H_{6}\) and hence the enthalpy change for the formation of \(C_{6} H_{6}\) from \(\mathrm{C}_{2} \mathrm{H}_{2}\).

Questions & Answers

QUESTION:

Acetylene \(\left(\mathrm{C}_{2} \mathrm{H}_{2}\right)\) and benzene \(\left(C_{6} H_{6}\right)\) have the same empirical formula. In fact, benzene can be made from acetylene as follows:

\(3 \mathrm{C}_{2} \mathrm{H}_{2}(g) \rightarrow \mathrm{C}_{6} \mathrm{H}_{6}(l)\)

The enthalpies of combustion for \(\mathrm{C}_{2} \mathrm{H}_{2}\) and \(C_{6} H_{6}\) are - 1299.4 kJ/mol and -3267.4 kJ/mol, respectively. Calculate the standard enthalpies of formation of \(\mathrm{C}_{2} \mathrm{H}_{2}\) and \(C_{6} H_{6}\) and hence the enthalpy change for the formation of \(C_{6} H_{6}\) from \(\mathrm{C}_{2} \mathrm{H}_{2}\).

ANSWER:

Step 1 of 5

The combustion reaction of acetylene is as follows;

                 

 

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