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Solved: A gas expands in volume from 26.7 mL to 89.3 mL at
Chapter 6, Problem 16P(choose chapter or problem)
A gas expands in volume from 26.7 mL to 89.3 mL at constant temperature. Calculate the work done (in joules) if the gas expands
(a) against a vacuum
(b) against a constant pressure of 1.5 atm, and
(c) against a constant pressure of 2.8 atm
Questions & Answers
QUESTION:
A gas expands in volume from 26.7 mL to 89.3 mL at constant temperature. Calculate the work done (in joules) if the gas expands
(a) against a vacuum
(b) against a constant pressure of 1.5 atm, and
(c) against a constant pressure of 2.8 atm
ANSWER:
Step 1 of 3
Given:
Initial volume \(\left(\mathrm{V}_{\text {intial }}\right)=26.7 \mathrm{~mL}\)
Final volume \(\left(\mathrm{V}_{\text {final }}\right)=89.3 \mathrm{~mL}\)
(a) Here, we are asked to calculate the work done (in joules) if gas expands against a vacuum
Because the external pressure is zero, no work is done in the expansion.
The work done (w) is calculated using the formula shown below:
\(\mathrm{w}=-\mathrm{P} \Delta \mathrm{V}\)
Where P = pressure
\(\Delta \mathrm{V}=\mathrm{V}_{\text {final }}-\mathrm{V}_{\text {intial }}\)
\(\begin{aligned} \Delta \mathrm{V} & =89.3 \mathrm{~mL}-26.7 \mathrm{~mL} \\ & =62.6 \mathrm{~mL} \end{aligned}\)
Now,
\(\begin{aligned} \mathrm{w} & =-0 \times 62.6 \\ & =0 \end{aligned}\)
Hence, the work done against a vacuum is \(0 J\).