The speed of a molecule in a uniform gas at equilibrium is

Chapter 6, Problem 29E

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QUESTION:

The speed of a molecule in a uniform gas at equilibrium is a random variable \(V\) whose density function is given by

\(f(v)=a v^{2} e^{-b r^{2}}, v>0\)

where \(b=m / 2 k T\) and \(k, T\), and \(m\) denote Boltzmann's constant, the absolute temperature, and the mass of the molecule, respectively.
a. Derive the distribution of  \(W=m V^{2} / 2\), the kinetic energy of the molecule.
b Find \(E(W)\).

Equation Transcription:

Text Transcription:

V

f(v)=av^2e^-br^2, v>0

b=m/2kt

k,T

m

W=mV^2/2

E(W)

Questions & Answers

QUESTION:

The speed of a molecule in a uniform gas at equilibrium is a random variable \(V\) whose density function is given by

\(f(v)=a v^{2} e^{-b r^{2}}, v>0\)

where \(b=m / 2 k T\) and \(k, T\), and \(m\) denote Boltzmann's constant, the absolute temperature, and the mass of the molecule, respectively.
a. Derive the distribution of  \(W=m V^{2} / 2\), the kinetic energy of the molecule.
b Find \(E(W)\).

Equation Transcription:

Text Transcription:

V

f(v)=av^2e^-br^2, v>0

b=m/2kt

k,T

m

W=mV^2/2

E(W)

ANSWER:

Solution :

Step 1 of 2:

Let the speed of a molecule in a uniform gas at equilibrium is a random variable V whose density function is given by

Where b=and k, T and m denote Boltzmann's constant.

Our goal is:

a). We need to derive the distribution of , kinetic energy of the molecule.

b). We need to find E(W).

Now we have derive the distribution of , kinetic energy of the molecule.

We know that , and .

Then,

,W0.

The above expression in the form of a gamma density, so the constant must be chosen so that the density integrate to 1, or simply

Therefore is .


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