Solved: The rate law for the reaction 2H2(g) 1 2NO(g)

Chapter 13, Problem 13.58

(choose chapter or problem)

The rate law for the reaction 2H2(g) 1 2NO(g) N2(g) 1 2H2O(g) is rate 5 k[H2][NO]2 . Which of the following mechanisms can be ruled out on the basis of the observed rate expression? Mechanism I H2 NO 88n H2O N (slow) N NO 88n N2 O (fast) O H2 88n H2O (fast) Mechanism II H2 2NO 88n N2O H2O (slow) N2O H2 88n N2 H2O (fast) Mechanism III 2NO 34 N2O2 (fast equilibrium) N2O2 H2 88n N2O H2O (slow) N2O H2 88n N2 H2O (fast)

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