In the oxidation of D-allose to D-allonic acid, a lactone having the general structure A

Chapter 27, Problem 27.62

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In the oxidation of D-allose to D-allonic acid, a lactone having the general structure A is isolated. Draw a stepwise mechanism to account for the formation of A. Use wedges and dashes to indicate the stereochemistry of all stereogenic centers in A. COOH CH2OH H OH H OH H OH H OH D-allonic acid A OH O OH HO HO O

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