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To determine the formation constant of a I: 1 complex. the absorbances belowwere

Principles of Instrumental Analysis | 6th Edition | ISBN: 9780495012016 | Authors: Douglas A. Skoog F. James Holler Stanley R. Crouch ISBN: 9780495012016 317

Solution for problem 14-23 Chapter 14

Principles of Instrumental Analysis | 6th Edition

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Principles of Instrumental Analysis | 6th Edition | ISBN: 9780495012016 | Authors: Douglas A. Skoog F. James Holler Stanley R. Crouch

Principles of Instrumental Analysis | 6th Edition

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Problem 14-23

To determine the formation constant of a I: 1 complex. the absorbances belowwere measured at 470 nm in a 2.50-cm cell for the ligand concentrations shown.The total metal concentration was CM = 7.50 X 10 4 M.(a) Use linear regression and the Benesi-Hildebrand equation (Equation 1411)to determine the formation constant and the difference in molar absorptivitiesat 470 nm.(b) Use nonlinear regression and Equation 14-10 to find the values of K, and j.e.Start with initial estimates of K, = 50 and j.e = 50.

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Nomenclature Rules for Coordination Chemistry  In naming complexes that are salts o The name of the cation is given before the name of the anion  In naming complex ions or molecules o The ligands are named before the metal o Ligands are listed in alphabetical order, regardless of their charges  The names of anionic ligands end in the letter “o” the...

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Chapter 14, Problem 14-23 is Solved
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Textbook: Principles of Instrumental Analysis
Edition: 6
Author: Douglas A. Skoog F. James Holler Stanley R. Crouch
ISBN: 9780495012016

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To determine the formation constant of a I: 1 complex. the absorbances belowwere

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