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Given the Fischer projection of the branched-chain carbohydrate (+)-d-apiose: (a) How

Chapter 23, Problem 23.32

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QUESTION:

Given the Fischer projection of the branched-chain carbohydrate \(\text { (+)-D-apiose: }\)

(a) How many chirality centers are in the open-chain form of \(D-apiose\)?

(b) Does d-apiose form an optically active alditol on reduction?

(c) How many chirality centers are in the furanose forms of \(D-apiose\)?

(d) How many stereoisomeric furanose forms of \(D-apiose\) are possible? Write their Haworth formulas.

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QUESTION:

Given the Fischer projection of the branched-chain carbohydrate \(\text { (+)-D-apiose: }\)

(a) How many chirality centers are in the open-chain form of \(D-apiose\)?

(b) Does d-apiose form an optically active alditol on reduction?

(c) How many chirality centers are in the furanose forms of \(D-apiose\)?

(d) How many stereoisomeric furanose forms of \(D-apiose\) are possible? Write their Haworth formulas.

ANSWER:

Step 1 of 6

Fischer projection:It is possible to represent the three-dimensional form of an organic molecule in two-dimensional form using horizontal lines. This representation is known as Fischer projection. The Fischer projections are mainly used to represent the two-dimensional representation of carbohydrates.

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