Suppose that (a) the attractive interactions between gas particles can be neglected, (b)

Chapter 3, Problem 3.34

(choose chapter or problem)

Suppose that (a) the attractive interactions between gas particles can be neglected, (b) the attractive interaction is dominant in a van der Waals gas, and the pressure is low enough to make the approximation 4ap/(RT)2 << 1. Find expressions for the fugacity of a van der Waals gas in terms of the pressure and estimate its value for ammonia at 10.00 atm and 298.15 K in each case.

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