The angular NO2 molecule has a single unpaired electron and can be trapped in a solid

Chapter 15, Problem 15.8

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The angular NO2 molecule has a single unpaired electron and can be trapped in a solid matrix or prepared inside a nitrite crystal by radiation damage of NO2 ions. When the applied field is parallel to the OO direction the centre of the spectrum lies at 333.64 mT in a spectrometer operating at 9.302 GHz. When the field lies along the bisector of the ONO angle, the resonance lies at 331.94 mT. What are the g-values in the two orientations?

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