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Solved: How many moles and numbers of ions of each type
Chapter 4, Problem 14P(choose chapter or problem)
How many moles and numbers of ions of each type are present in the following aqueous solutions?
(a) 130. mLof 0.45M aluminum chloride
(b) 9.80 mLof a solution containing 2.59 g lithium sulfate/L
(c) 245 mL of a solution containing 3.68 × 1022 formula units of potassium bromide per liter
Questions & Answers
QUESTION: Problem 14P
How many moles and numbers of ions of each type are present in the following aqueous solutions?
(a) 130. mLof 0.45M aluminum chloride
(b) 9.80 mLof a solution containing 2.59 g lithium sulfate/L
(c) 245 mL of a solution containing 3.68 × 1022 formula units of potassium bromide per liter
ANSWER:
Solution 14P
Here we have to calculate how many moles and numbers of ions of each type are present in the following aqueous solutions.
Step 1
(a) 130. mL of 0.45M aluminum chloride
1st we have to write the chemical reaction for the dissociation of AlCl3 (aluminum chloride)
AlCl3 (s) → Al3+(aq) + 3 Cl-(aq)
In the above reaction it has been found that 1 mol of Al3+ and 3 mole of Cl- is dissolved per mole of AlCl3.
In this question it has been given that molarity of AlCl3 is 0.45 M and volume is 130 mL.
Mole of Al 3+ formed from AlCl3 :-
130 mL of
= 0.059 mol of Al3+
Mole of Cl - formed from AlCl3 :-
130 mL of
= 0.176 mol of Cl-
Number of Al3+ and Cl - ions:-
Number of ions can be obtained by multiplying mole with Avogadro’s number, thus
Number of Al3+ ion = 0.059 mol of Al3+ = 0.3551023 Al3+ ions
Number of Cl- ion = 0.176 mol of Cl- = 1.061023 Cl- ions
Thus the mole of Al3+ and Cl- ion is found to be 0.059 mole and 0.176 mole & number of ions is found to be 0.3551023 Al3+ ions and 1.061023 Cl- ions.