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Molecular iodine,I2(g),dissociates into iodine atoms at 625 K with a first-order rate

Chapter 20, Problem 14.44

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QUESTION:

Molecular iodine,, dissociates into iodine atoms at 625 K with a first-order rate constant of  .(a) What is the half-life for this reaction? (b) If you start with 0.050 M  at this temperature, how much will remain after 5.12 s assuming that the iodine atoms do not recombine to form   ?

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QUESTION:

Molecular iodine,, dissociates into iodine atoms at 625 K with a first-order rate constant of  .(a) What is the half-life for this reaction? (b) If you start with 0.050 M  at this temperature, how much will remain after 5.12 s assuming that the iodine atoms do not recombine to form   ?

ANSWER:

Step 1 of 3

First-order reactions represent reactions where the rate is dependent on one reactant’s concentration. If the reactant concentration is doubled in this reaction, the reaction rate also gets doubled.

The half-life denotes the time needed for the reactant concentration to approach half the value of the initial value. The connection between the half-life and reaction rate constant can be given as:

                                                         

Where

 represents the half-life.

k represents the rate constant.

 

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