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Solutions for Chapter 16: Nuclear Magnetic Resonance Spectroscopy

Organic Chemistry,  - Standalone Book | 2nd Edition | ISBN: 9781118452288 | Authors: David R. Klein

Full solutions for Organic Chemistry, - Standalone Book | 2nd Edition

ISBN: 9781118452288

Organic Chemistry,  - Standalone Book | 2nd Edition | ISBN: 9781118452288 | Authors: David R. Klein

Solutions for Chapter 16: Nuclear Magnetic Resonance Spectroscopy

Solutions for Chapter 16
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Textbook: Organic Chemistry, - Standalone Book
Edition: 2
Author: David R. Klein
ISBN: 9781118452288

This textbook survival guide was created for the textbook: Organic Chemistry, - Standalone Book, edition: 2. Chapter 16: Nuclear Magnetic Resonance Spectroscopy includes 76 full step-by-step solutions. Organic Chemistry, - Standalone Book was written by and is associated to the ISBN: 9781118452288. This expansive textbook survival guide covers the following chapters and their solutions. Since 76 problems in chapter 16: Nuclear Magnetic Resonance Spectroscopy have been answered, more than 72818 students have viewed full step-by-step solutions from this chapter.

Key Chemistry Terms and definitions covered in this textbook
  • catenation.

    The ability of the atoms of an element to form bonds with one another. (22.3)

  • closest packing.

    The most efficient arrangements for packing atoms, molecules, or ions in a crystal. (11.4)

  • copolymer

    A complex polymer resulting from the polymerization of two or more chemically different monomers. (Section 12.8)

  • deactivate

    For a substitutedaromatic ring, the effect of an electronwithdrawingsubstituent that decreases therate of electrophilic aromatic substitution.

  • Dieckmann cyclization

    An intramolecular Claisen condensation.

  • Dihedral angle

    The angle created by two intersecting planes.

  • dihydroxylation

    A reaction characterized by the addition of two hydroxyl groups (OH) across an alkene.

  • dispersion forces

    Intermolecular forces resulting from attractions between induced dipoles. Also called London dispersion forces. (Section 11.2)

  • donor atom

    The atom of a ligand that bonds to the metal. (Section 23.2)

  • Edman degradatio

    A method for selectively cleaving and identifying the N-terminal amino acid of a polypeptide chain.

  • frontier orbital theory

    The analysis of a reaction using MO theory, where only the frontier orbitals (HOMO and LUMO) are considered.

  • ionic solids

    Solids that are composed of ions. (Section 12.1)

  • Markovnikov’s rule

    In the addition of HX, H2O, or ROH to an alkene, hydrogen adds to the carbon of the double bond having the greater number of hydrogens.

  • Meta (m)

    Refers to groups occupying 1,3-positions on a benzene ring.

  • off-resonance decoupling

    In NMR spectroscopy, a technique in which only the one-bond couplings are observed. CH3 groups appear as quartets, CH2 groups appear as triplets, CH groups appear as doublets, and quaternary carbon atoms appear as singlets.

  • periplanar

    A conformation in which a hydrogen atom and a leaving group are approximately coplanar.

  • polar reaction

    A reaction that involves the participation of ions as reactants, intermediates, or products.

  • semiconductor

    A material that has electrical conductivity between that of a metal and that of an insulator. (Section 12.7)

  • sigmatropic rearrangements

    A pericyclic reaction in which one s bond is formed at the expense of another.

  • Zwitterion

    An internal salt of an amino acid; the carboxylate is negatively charged, and the ammonium group is positively charged

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