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Solutions for Chapter 14: Organic Chemistry 8th Edition

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Full solutions for Organic Chemistry | 8th Edition

ISBN: 9780321768414

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Solutions for Chapter 14

Solutions for Chapter 14
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Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

Chapter 14 includes 50 full step-by-step solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. Since 50 problems in chapter 14 have been answered, more than 232746 students have viewed full step-by-step solutions from this chapter. Organic Chemistry was written by and is associated to the ISBN: 9780321768414. This expansive textbook survival guide covers the following chapters and their solutions.

Key Chemistry Terms and definitions covered in this textbook
  • bond enthalpy

    The enthalpy change, ?H, required to break a particular bond when the substance is in the gas phase. (Section 8.8)

  • complex lipid

    A lipid that readily undergoes hydrolysis in aqueous acid or base to produce smaller fragments.

  • copolymer

    A polymer that is constructed from more than one repeating unit.

  • Electron affinity

    Energy added or released when an electron is added to an atom or molecule.

  • ester

    An organic compound that has an OR group attached to a carbonyl; it is the product of a reaction between a carboxylic acid and an alcohol. (Section 24.4)

  • free induction decay

    In NMR spectroscopy, a complex signal which is a combination of all of the electrical impulses generated by each type of proton.

  • haloform reaction

    A reaction in which a methyl ketone is converted into a carboxylic acid upon treatment with excess base and excess halogen, followed by aqueous acid.

  • Hertz (Hz)

    The unit in which frequency is measured: s 21 (read “per second”).

  • Hydrogenolysis

    Cleavage of a single bond by H2, most commonly accomplished by treating a compound with H2 in the presence of a transition metal catalyst.

  • ideal solution

    A solution that obeys Raoult’s law. (Section 13.5)

  • intermediate

    A substance formed in one elementary step of a multistep mechanism and consumed in another; it is neither a reactant nor an ultimate product of the overall reaction. (Section 14.6)

  • Keto-enol tautomerism

    A type of isomerism involving keto (from ketone) and enol tautomers

  • lactone

    A cyclic ester.

  • Lewis acid

    A compound capable offunctioning as an electron pair acceptor.

  • nitrosonium ion

    The NO+ ion, which is formed when NaNO2 is treated with HCl.

  • off-resonance decoupling

    In NMR spectroscopy, a technique in which only the one-bond couplings are observed. CH3 groups appear as quartets, CH2 groups appear as triplets, CH groups appear as doublets, and quaternary carbon atoms appear as singlets.

  • overall reaction order

    The sum of the reaction orders of all the reactants appearing in the rate expression when the rate can be expressed as rate = k3A4a 3B4b... . (Section 14.3)

  • periplanar

    A conformation in which a hydrogen atom and a leaving group are approximately coplanar.

  • Tertiary structure of proteins

    The three-dimensional arrangement in space of all atoms in a single polypeptide chain.

  • Tripeptide

    A molecule containing three amino acid units, each joined to the next by a peptide bond

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