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Solved: Determine the molecular formula for each of the

Chapter 14, Problem 5P

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QUESTION:

Problem 5P

Determine the molecular formula for each of the following:

a. a compound that contains only C and H and has a molecular ion with an m/z value of 72

b. a compound that contains C, H, and one O and has a molecular ion with an m/z value of 100

c. a compound that contains C, H, and two Os and has a molecular ion with an m/z value of 102

d. an amide that has a molecular ion with an m/z value of 115

Questions & Answers

QUESTION:

Problem 5P

Determine the molecular formula for each of the following:

a. a compound that contains only C and H and has a molecular ion with an m/z value of 72

b. a compound that contains C, H, and one O and has a molecular ion with an m/z value of 100

c. a compound that contains C, H, and two Os and has a molecular ion with an m/z value of 102

d. an amide that has a molecular ion with an m/z value of 115

ANSWER:

Solution  5P

(a)

The compound has m/z value of 72. If we divide the m/z value by 13 then we get 5 and the remainder will be 7. So, it indicates that the molecule contains only C and H in it.

Thus, number of carbons in the molecule is 5 and the number of hydrogen atoms in the molecule is.

Hence molecular formula is .

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