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The cyanate ion (OCN-) and the fulminate ion (CNO-) share

Chemistry: A Molecular Approach | 3rd Edition | ISBN: 9780321809247 | Authors: Nivaldo J. Tro ISBN: 9780321809247 1

Solution for problem 97E Chapter 9

Chemistry: A Molecular Approach | 3rd Edition

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Chemistry: A Molecular Approach | 3rd Edition | ISBN: 9780321809247 | Authors: Nivaldo J. Tro

Chemistry: A Molecular Approach | 3rd Edition

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Problem 97E

The cyanate ion (OCN-) and the fulminate ion (CNO-) share the same three atoms but have vastly different properties. The cyanate ion is stable, while the fulminate ion is unstable and forms explosive compounds. The resonance structures of the cyanate ion were explored in Example 9.8 . Draw Lewis structures for the fulminate ion—including possible resonance forms—and use formal charge to explain why the fulminate ion is less stable (and therefore more reactive) than the cyanate ion.

REFERENCE:

Step-by-Step Solution:

Solution 97 E Step 1 of 2 The most likely form for cyanate ion is the one indicated below In fact If we calculate Formal charge for each atom For C Valence electrons - Lone pair electrons - ½ bondin electrons= 4-0-4= 0 For O Valence electrons - Lone pair electrons - ½ bondin electrons= 6-6-1=-1 For N Valence electrons - Lone pair electrons - ½ bondin electrons= 5-2-3=0 O carries the(-) charge and it’s the most electronegative atom

Step 2 of 2

Chapter 9, Problem 97E is Solved
Textbook: Chemistry: A Molecular Approach
Edition: 3
Author: Nivaldo J. Tro
ISBN: 9780321809247

Since the solution to 97E from 9 chapter was answered, more than 2598 students have viewed the full step-by-step answer. This textbook survival guide was created for the textbook: Chemistry: A Molecular Approach, edition: 3. Chemistry: A Molecular Approach was written by and is associated to the ISBN: 9780321809247. This full solution covers the following key subjects: ion, fulminate, cyanate, resonance, stable. This expansive textbook survival guide covers 82 chapters, and 9454 solutions. The answer to “The cyanate ion (OCN-) and the fulminate ion (CNO-) share the same three atoms but have vastly different properties. The cyanate ion is stable, while the fulminate ion is unstable and forms explosive compounds. The resonance structures of the cyanate ion were explored in Example 9.8 . Draw Lewis structures for the fulminate ion—including possible resonance forms—and use formal charge to explain why the fulminate ion is less stable (and therefore more reactive) than the cyanate ion.REFERENCE:” is broken down into a number of easy to follow steps, and 77 words. The full step-by-step solution to problem: 97E from chapter: 9 was answered by , our top Chemistry solution expert on 02/22/17, 04:35PM.

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The cyanate ion (OCN-) and the fulminate ion (CNO-) share

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