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The following equilibrium constant have been determined

Chapter 14, Problem 30P

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QUESTION:

The following equilibrium constants have been determined for oxalic acid at \(25^{\circ} \mathrm{C}\):

\(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(a q)\ \leftrightharpoons\ H^{+}(a q)+\mathrm{HC}_{2} \mathrm{O}_{4}^{-}(a q)\)

                                                   \(K_{c}^{\prime}=6.5 \times 10^{-2}\)

\(\mathrm{HC}_{2} \mathrm{O}_{4}^{-}(a q)\ \leftrightharpoons\ H^{+}(a q)+\mathrm{C}_{2} O_{4}^{2-}(a q)\)

                                                   \(K_{c}^{\prime \prime}=6.1 \times 10^{-5}\)

Calculate the equilibrium constant for the following reaction at the same temperature:

\(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(a q)\ \leftrightharpoons\ 2 \mathrm{H}^{+}(a q)+\mathrm{C}_{2} \mathrm{O}_{4}^{2-}(a q)\)

Questions & Answers

QUESTION:

The following equilibrium constants have been determined for oxalic acid at \(25^{\circ} \mathrm{C}\):

\(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(a q)\ \leftrightharpoons\ H^{+}(a q)+\mathrm{HC}_{2} \mathrm{O}_{4}^{-}(a q)\)

                                                   \(K_{c}^{\prime}=6.5 \times 10^{-2}\)

\(\mathrm{HC}_{2} \mathrm{O}_{4}^{-}(a q)\ \leftrightharpoons\ H^{+}(a q)+\mathrm{C}_{2} O_{4}^{2-}(a q)\)

                                                   \(K_{c}^{\prime \prime}=6.1 \times 10^{-5}\)

Calculate the equilibrium constant for the following reaction at the same temperature:

\(\mathrm{H}_{2} \mathrm{C}_{2} \mathrm{O}_{4}(a q)\ \leftrightharpoons\ 2 \mathrm{H}^{+}(a q)+\mathrm{C}_{2} \mathrm{O}_{4}^{2-}(a q)\)

ANSWER:

Step 1 of 2

 The equilibrium constant for the oxalic acid is given as follows.

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