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Check the Clausius-Mossotti relation (Eq. 4.72) for the

Chapter 4, Problem 42P

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QUESTION:

Problem 42P

Check the Clausius-Mossotti relation (Eq. 4.72) for the gases listed in Table 4.1. (Dielectric constants are given in Table 4.2.) (The densities here are so small that Eqs. 4.70 and 4.72 are indistinguishable. For experimental data that confirm the Clausius-Mossotti correction term see, for instance, the first edition of Purcell’s Electricity and Magnetism, Problem 9.28.)23

Reference equation 4.72

Reference equation 4.70

Reference table 4.1

Reference table 4.2

Questions & Answers

QUESTION:

Problem 42P

Check the Clausius-Mossotti relation (Eq. 4.72) for the gases listed in Table 4.1. (Dielectric constants are given in Table 4.2.) (The densities here are so small that Eqs. 4.70 and 4.72 are indistinguishable. For experimental data that confirm the Clausius-Mossotti correction term see, for instance, the first edition of Purcell’s Electricity and Magnetism, Problem 9.28.)23

Reference equation 4.72

Reference equation 4.70

Reference table 4.1

Reference table 4.2

ANSWER:

Solution 42P

Step 1 of 4:

Clausius-Mossotti relation explains the relationship between the atomic polarizability, susceptibility, and the dielectric constant of a material. We are going to check the susceptibility for the gases listed in the table and verify them with both equations 4.72 and 4.7.

The given equations

Where         is the molecular susceptibility

  is the molecular polarizability

         is the number density of the molecules

         is the dielectric constant

         is the permittivity of free space

NA  is avogadro number

Vi is volume of the ideal gas

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