(a) Using average bond enthalpies, predict which of the

Chapter 5, Problem 76E

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QUESTION:

(a) Using average bond enthalpies, predict which of the following reactions will be most exothermic:

\(\begin{array}{l}\text{(i) }\mathrm{C}(\mathrm{g})+2\mathrm{\ F}_2(\mathrm{g})\longrightarrow\mathrm{CF}_4(\mathrm{g})\\ \text{(ii) }\mathrm{CO}(\mathrm{g})+3\mathrm{\ F}_2\longrightarrow\mathrm{CF}_4(\mathrm{g})+\mathrm{OF}_2(\mathrm{g})\\ \text{(iii) }\mathrm{CO}_2(g)+4\mathrm{\ F}_2\longrightarrow\mathrm{CF}_4(g)+2\mathrm{OF}_2(g)\end{array}\)

(b) Explain the trend, if any, that exists between reaction exothermicity and the extent to which the carbon atom is bonded to oxygen.

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QUESTION:

(a) Using average bond enthalpies, predict which of the following reactions will be most exothermic:

\(\begin{array}{l}\text{(i) }\mathrm{C}(\mathrm{g})+2\mathrm{\ F}_2(\mathrm{g})\longrightarrow\mathrm{CF}_4(\mathrm{g})\\ \text{(ii) }\mathrm{CO}(\mathrm{g})+3\mathrm{\ F}_2\longrightarrow\mathrm{CF}_4(\mathrm{g})+\mathrm{OF}_2(\mathrm{g})\\ \text{(iii) }\mathrm{CO}_2(g)+4\mathrm{\ F}_2\longrightarrow\mathrm{CF}_4(g)+2\mathrm{OF}_2(g)\end{array}\)

(b) Explain the trend, if any, that exists between reaction exothermicity and the extent to which the carbon atom is bonded to oxygen.

ANSWER:

 

Step 1 of 6

(A) To calculate the enthalpy change using bond enthalpy.

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