Solutions for Chapter 6: General Chemistry: Principles and Modern Applications 10th Edition

The minimum energy needed for reaction; the height of the energy barrier to formation of products. (Section 14.5)

Attraction between unlike molecules. (11.3)

A negatively charged ion. (Section 2.7)

An elementary reaction that involves two molecules. (Section 14.6)

A [3,3] sigmatropic rearrangement that is observed for allylic vinylic ethers.

An effect that causes different regions of space to be characterized by different magnetic field strengths.

The difference in total bond strengths and solvation between various points under comparison on a reaction coordinate diagram

When orbitals of equal energy are available but there are not enough electrons to fi ll all of them completely, one electron is put in each before a second electron is added to any

The attractive interaction between a hydrogen atom bonded to an atom of high electronegativity (most commonly O or N) and a lone pair of electrons on another atom of high electronegativity (again, most commonly O or N).

A polar group that has favorable interactions with water.

The difference between the mass of a nucleus and the total masses of the individual nucleons that it contains. (Section 21.6)

A compound that consists of molecules. (Section 2.6)

An insoluble substance that forms in, and separates from, a solution. (Section 4.2)

A crystal lattice in which the lattice points are located only at the corners of each unit cell. (Section 12.2)

Elimination of two substituents at a metal center, causing the oxidation state of the metal to decrease by two.

The ordered arrangements (conformations) of amino acids in localized regions of a polypeptide or protein

A molecular orbital in which electron density is concentrated between two nuclei, along the axis joining them, and is cylindrically symmetrical

A reaction with a negative DG, which means that products are favored at equilibrium.

A compound or region of a compound that is very bulky.

A protein used to transport molecules or ions from one location to another. Hemoglobin is a classic example of a transport protein, used to transport molecular oxygen from the lungs to all the tissues of the body.