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Identify the compound that has an M 1 1 ion at mYz 5 136 in its CI mass spectrum, an IR
Chapter 23, Problem 23.4(choose chapter or problem)
Identify the compound that has an M 1 1 ion at mYz 5 136 in its CI mass spectrum, an IR absorption at 3279 cm1 , and the following NMR spectrum: d 0.91 (1H, s), d 1.07 (3H, t, J 5 7 Hz), d 2.60 (2H, q, J 5 7 Hz), d 3.70 (2H, s), d 7.18 (5H, apparent s).
Questions & Answers
QUESTION:
Identify the compound that has an M 1 1 ion at mYz 5 136 in its CI mass spectrum, an IR absorption at 3279 cm1 , and the following NMR spectrum: d 0.91 (1H, s), d 1.07 (3H, t, J 5 7 Hz), d 2.60 (2H, q, J 5 7 Hz), d 3.70 (2H, s), d 7.18 (5H, apparent s).
ANSWER:Problem 23.4
Identify the compound that has an M 1 1 ion at mYz 5 136 in its CI mass spectrum, an IR absorption at 3279 cm1 , and the following NMR spectrum: d 0.91 (1H, s), d 1.07 (3H, t, J 5 7 Hz), d 2.60 (2H, q, J 5 7 Hz), d 3.70 (2H, s), d 7.18 (5H, apparent s).
Step by Step Solution
Step 1 of 2
From the given,
Cl mass spectrum the ion has .
Hence, its mass comes out to be 135.
Therefore, according to the nitrogen rule it has an odd number of nitrogen atoms.
IR absorption at .
This value indicates secondary amine stretching.