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Solutions for Chapter 15: Organic Chemistry 7th Edition

Organic Chemistry | 7th Edition | ISBN: 9781269406772 | Authors: Paula Yurkanis Bruice

Full solutions for Organic Chemistry | 7th Edition

ISBN: 9781269406772

Organic Chemistry | 7th Edition | ISBN: 9781269406772 | Authors: Paula Yurkanis Bruice

Solutions for Chapter 15

Solutions for Chapter 15
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Textbook: Organic Chemistry
Edition: 7
Author: Paula Yurkanis Bruice
ISBN: 9781269406772

Organic Chemistry was written by and is associated to the ISBN: 9781269406772. Chapter 15 includes 108 full step-by-step solutions. Since 108 problems in chapter 15 have been answered, more than 190866 students have viewed full step-by-step solutions from this chapter. This expansive textbook survival guide covers the following chapters and their solutions. This textbook survival guide was created for the textbook: Organic Chemistry, edition: 7.

Key Chemistry Terms and definitions covered in this textbook
  • accuracy

    A measure of how closely individual measurements agree with the correct value. (Section 1.5)

  • acid ionization constant (Ka).

    The equilibrium constant for the acid ionization. (15.5)

  • allylic bromination

    A radical reaction that achieves installation of a bromine atom at an allylic position.

  • blocking group

    A group that can be readily installed and uninstalled. Used for regiochemical control during synthesis.

  • Carbocation

    A species in which a carbon atom has only six electrons in its valence shell and bears a positive charge

  • Dienophile

    A compound containing a double bond (consisting of one or two C, N, or O atoms) that can react with a conjugated diene to give a Diels-Alder adduct.

  • Electrophilic aromatic substitution

    A reaction in which there is substitution of an electrophile, E1, for a hydrogen on an aromatic ring

  • enantiomeric excess

    For a mixture containing two enantiomers, the difference between the percent concentration of the major enantiomer and the percent concentration of its mirror image.

  • Enantioselective reaction

    A reaction that produces one enantiomer in preference to the other.

  • ether

    A compound with the structure R!O!R.

  • fishhook arrow

    A curved arrow with only one barb, indicating the motion of just one electron (also see Sect. 11.1).

  • Ketose

    A monosaccharide containing a ketone group.

  • LUMO

    The lowest unoccupied molecular orbital.

  • microstate

    The state of a system at a particular instant; one of many possible energetically equivalent ways to arrange the components of a system to achieve a particular state. (Section 19.3)

  • overall reaction order

    The sum of the reaction orders of all the reactants appearing in the rate expression when the rate can be expressed as rate = k3A4a 3B4b... . (Section 14.3)

  • pressure–volume (PV) work

    Work performed by expansion of a gas against a resisting pressure. (Section 5.3)

  • primary structure

    The sequence of amino acids along a protein chain. (Section 24.7)

  • reductive amination

    The conversion of a ketone or aldehyde into an imine under conditions in which the imine is reduced as soon as it is formed, giving an amine.

  • Restriction endonuclease

    An enzyme that catalyzes the hydrolysis of a particular phosphodiester bond within a DNA strand.

  • smectic liquid crystalline phase

    A liquid crystal in which the molecules are aligned along their long axes and arranged in sheets, with the ends of the molecules aligned. There are several different kinds of smectic phases. (Section 12.8)

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