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Chapter 4, Problem 4.37

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QUESTION:

What is an oxidation number? How is it used to identify redox reactions? Explain why, except for ionic compounds, oxidation number does not have any physical significance

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QUESTION:

What is an oxidation number? How is it used to identify redox reactions? Explain why, except for ionic compounds, oxidation number does not have any physical significance

ANSWER:

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Oxidation number is defined as the charge that an atom has or appears to have when electrons are distributed according to certain rules.

Rules to assign the oxidation number;

*   The oxidation number of the atoms in any free uncombined element is zero.

*   The sum of the oxidation numbers of all atoms in a compound is zero.

*   The sum of the oxidation numbers of all atoms in an ion is equal to the charge of the ion.

*   The oxidation number of fluorine in all its compounds is -1.

*   The oxidation number of other halogen in their compounds is usually -1.

 

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