For each pair of compounds, circle the compound you expect to have the higher boiling

QUESTION:

For each pair of compounds, circle the compound you expect to have the higher boiling point. Explain your reasoning.

(a) \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{C}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{3}\) or \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CH}-\mathrm{CH}_{2} \mathrm{CH}_{2}-\mathrm{CH}\left(\mathrm{CH}_{3}\right)_{2}\)

(b) \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{6} \mathrm{CH}_{3}\) or \(\mathrm{CH}_{3}\left(\mathrm{CH}_{2}\right)_{5} \mathrm{CH}_{2} \mathrm{OH}\)

(c) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}_{2} \mathrm{CH}_{3}\) or \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\)

(d) \(\mathrm{HOCH}_{2}-\left(\mathrm{CH}_{2}\right)_{4}-\mathrm{CH}_{2} \mathrm{OH}\) or \(\left(\mathrm{CH}_{3}\right)_{3} \mathrm{CCH}(\mathrm{OH}) \mathrm{CH}_{3}\)

(e) \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2}\right)_{2} \mathrm{NH}\) or \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2}\right)_{3} \mathrm{N}\)

(f) or