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A reluctant first-order substrate can be forced to ionize

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr ISBN: 9780321768414 33

Solution for problem 29P Chapter 6

Organic Chemistry | 8th Edition

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Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Organic Chemistry | 8th Edition

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Problem 29P

A reluctant first-order substrate can be forced to ionize by adding some silver nitrate (one ofthe few soluble silver salts) to the reaction. Silver ion reacts with the halogen to form a silverhalide (a highly exothermic reaction), generating the cation of the alkyl group.

Give mechanisms for the following silver-promoted rearrangements.

(a)

(b)

Step-by-Step Solution:
Step 1 of 3

mechanisms for the following silver-promoted rearrangements

a). Formation of primary carbocation.

b). Methyl shifting

c)....

Step 2 of 3

Chapter 6, Problem 29P is Solved
Step 3 of 3

Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. This full solution covers the following key subjects: silver, reaction, mechanisms, exothermic, few. This expansive textbook survival guide covers 25 chapters, and 1336 solutions. Organic Chemistry was written by and is associated to the ISBN: 9780321768414. Since the solution to 29P from 6 chapter was answered, more than 288 students have viewed the full step-by-step answer. The full step-by-step solution to problem: 29P from chapter: 6 was answered by , our top Chemistry solution expert on 05/06/17, 06:41PM. The answer to “A reluctant first-order substrate can be forced to ionize by adding some silver nitrate (one ofthe few soluble silver salts) to the reaction. Silver ion reacts with the halogen to form a silverhalide (a highly exothermic reaction), generating the cation of the alkyl group. Give mechanisms for the following silver-promoted rearrangements.(a) (b)” is broken down into a number of easy to follow steps, and 52 words.

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