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When ethyl bromide is added to potassium tert-butoxide,

Chapter 8, Problem 48SP

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QUESTION:

When ethyl bromide is added to potassium tert-butoxide, the product is ethyl tert-butyl ether.

\(\mathrm{CH}_{3} \mathrm{CH}_{2}-\mathrm{Br}+\left(\mathrm{CH}_{3}\right)_{3} \mathrm{C}-\mathrm{O}^{-+} \mathrm{K} \rightarrow\left(\mathrm{CH}_{3}\right)_{3} \mathrm{C}-\mathrm{O}-\mathrm{CH}_{2} \mathrm{CH}_{3}\)

     ethyl bromide             potassium tert-butoxide             ethyl tert-butyl ether

(a) What happens to the reaction rate if the concentration of ethyl bromide is doubled?
(b) What happens to the rate if the concentration of potassium tert-butoxide is tripled and the concentration of ethyl bromide is doubled?
(c) What happens to the rate if the temperature is raised?

Equation Transcription:

Text Transcription:

CH_3CH_2-Br + (CH_3)_3C-O^-+K \rightarrow  (CH_3)_3C-O-CH_2CH_3

Questions & Answers

QUESTION:

When ethyl bromide is added to potassium tert-butoxide, the product is ethyl tert-butyl ether.

\(\mathrm{CH}_{3} \mathrm{CH}_{2}-\mathrm{Br}+\left(\mathrm{CH}_{3}\right)_{3} \mathrm{C}-\mathrm{O}^{-+} \mathrm{K} \rightarrow\left(\mathrm{CH}_{3}\right)_{3} \mathrm{C}-\mathrm{O}-\mathrm{CH}_{2} \mathrm{CH}_{3}\)

     ethyl bromide             potassium tert-butoxide             ethyl tert-butyl ether

(a) What happens to the reaction rate if the concentration of ethyl bromide is doubled?
(b) What happens to the rate if the concentration of potassium tert-butoxide is tripled and the concentration of ethyl bromide is doubled?
(c) What happens to the rate if the temperature is raised?

Equation Transcription:

Text Transcription:

CH_3CH_2-Br + (CH_3)_3C-O^-+K \rightarrow  (CH_3)_3C-O-CH_2CH_3

ANSWER:

Solution 48SP :

Step 1:

Given reaction :

When ethyl bromide is added to potassium tert-butoxide, the product is ethyl tert-butyl ether.

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