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(a) Using the BDEs in Table 4-2 (p. 143), compute the

Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr ISBN: 9780321768414 33

Solution for problem 17P Chapter 4

Organic Chemistry | 8th Edition

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Organic Chemistry | 8th Edition | ISBN: 9780321768414 | Authors: L.G. Wade Jr

Organic Chemistry | 8th Edition

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Problem 17P

(a) Using the BDEs in Table 4-2 (p. 143), compute the value of ΔH° for each step in the iodination of methane.

(b) Compute the overall value of ΔH° for iodination.

(c) Suggest two reasons why iodine does not react well with methane.

Step-by-Step Solution:
Step 1 of 3

Step-1

The iodination of methane can be carried out by the  following ways:-

I2  + CH3 I-CH3 + I .

Mechanism:-

1)Initiation:-

This step involves the generation of active species (free radical)

2) Propagation:-

This process involves the growth of a polymer chain by successive addition of monomers during propagation can be represented as follows:-

The value of ΔH° for each step in the formation of  iodination of methane can be calculate as,

For breaking I-I ,      ΔH° = +151 KJ/mole (+...

Step 2 of 3

Chapter 4, Problem 17P is Solved
Step 3 of 3

Textbook: Organic Chemistry
Edition: 8
Author: L.G. Wade Jr
ISBN: 9780321768414

This textbook survival guide was created for the textbook: Organic Chemistry, edition: 8. This full solution covers the following key subjects: compute, methane, Iodination, overall, bdes. This expansive textbook survival guide covers 25 chapters, and 1336 solutions. Organic Chemistry was written by and is associated to the ISBN: 9780321768414. The full step-by-step solution to problem: 17P from chapter: 4 was answered by , our top Chemistry solution expert on 05/06/17, 06:41PM. Since the solution to 17P from 4 chapter was answered, more than 282 students have viewed the full step-by-step answer. The answer to “(a) Using the BDEs in Table 4-2 (p. 143), compute the value of ?H° for each step in the iodination of methane.(b) Compute the overall value of ?H° for iodination.(c) Suggest two reasons why iodine does not react well with methane.” is broken down into a number of easy to follow steps, and 41 words.

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