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What is the boiling point of an aqueous solution that freezes at ?6.7 °C?

Chapter 13, Problem 127P

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QUESTION:

What is the boiling point of an aqueous solution that freezes at \(\mathrm{-6.7~^\circ C}\)?

Equation Transcription:

Text Transcription:

-6.7^oC

Questions & Answers

QUESTION:

What is the boiling point of an aqueous solution that freezes at \(\mathrm{-6.7~^\circ C}\)?

Equation Transcription:

Text Transcription:

-6.7^oC

ANSWER:

Solution: Here, we are going to determine the boiling point.

Step1:

The depression of freezing point of a solution is calculated by the equation:

 Tf  = m x Kf                --------(1)

Where m is the molality of the solution  and Kf is the  freezing point depression constant for the solvent.

Similarly, the elevation of boiling  point of a solution is calculated by the equation:

 Tb = m x Kb        --------(2)

Where m is the molality of the solution  and Kb is the  boiling point elevation constant for the solvent.

Step2:

The freezing point of water = 0oC

Freezing point of the solution = -6.7oC

Therefore, depression in freezing point(Tf  ) =  0oC - (-6.7oC)

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