One of the molecular orbitals of the H2- ion is sketched

Chapter , Problem 105AE

(choose chapter or problem)

One of the molecular orbitals of the \(\mathrm{H}_{2}^{-}\) ion is sketched below:

(a) Is the molecular orbital a \(\sigma \text { or } \pi \mathrm{MO}\) ? Is it bonding or antibonding?

(b) In \(\mathrm{H}_{2}^{-}\), how many electrons occupy the \(\mathrm{MO}\) shown above?

(c) What is the bond order in the \(\mathrm{H}_{2}^{-}\) ion?

(d) Compared to the \(\mathrm{H}-\mathrm{H}\)  bond in \(\mathrm{H}_{2}\), the \(\mathrm{H}-\mathrm{H}\) bond in \(\mathrm{H}_{2}^{-}\)  is expected to be which of the following:

(i) Shorter and stronger,

(ii) longer and stronger,

(iii) shorter and weaker,

(iv) longer and weaker, or

(v) the same length and strength?

Equation Transcription:

   

     

   

   

   

   

 

Text Transcription:

H2-

\sigma \text { or } \pi \mathrm{MO}

H2-      

MO    

H2-  

H-H    

H2  

H-H

H2-

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