Solved: Nonideal-Gas Behavior (Section)Table shows that
Chapter , Problem 98E(choose chapter or problem)
Problem 98E
Nonideal-Gas Behavior (Section)
Table shows that the van der Waals b parameter has units of L/mol. This means that we can calculate the sizes of atoms or molecules from the b parameter. Refer back to the discussion in Section. Is the van der Waals radius we calculate from the b parameter of Table 10.3 more closely associated with the bonding or nonbonding atomic radius discussed there? Explain.
Table Van der Waals Constants for Gas Molecules
Substance |
a(L2@atm/mol2) |
b(L/mol) |
He |
0.0341 |
0.02370 |
Ne |
0.211 |
0.0171 |
Ar |
1.34 |
0.0322 |
Kr |
2.32 |
0.0398 |
Xe |
4.19 |
0.0510 |
H2 |
0.244 |
0.0266 |
N2 |
1.39 |
0.0391 |
O2 |
1.36 |
0.0318 |
F2 |
1.06 |
0.0290 |
Cl2 |
6.49 |
0.0562 |
H2O |
5.46 |
0.0305 |
NH3 |
4.17 |
0.0371 |
CH4 |
2.25 |
0.0428 |
CO2 |
3.59 |
0.0427 |
CCl4 |
20.4 |
0.1383 |
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